Front Cover: Reductive Rearrangement of a 1‐Phospha‐2‐azanorbornene (Chem. Eur. J. 29/2021)
نویسندگان
چکیده
When fed the right food, hermit crab depicted in cover image grows bigger and finally needs a larger shell. This work reports reactivity of 1-phospha-2-azanorbornene, product hetero Diels-Alder reaction between 2H-phosphole an activated imine. Thus, reductive cleavage phosphorus−nitrogen bond with LiAlH4 leads to unprecedented ring expansion formation 1-phosphabicyclo[3.2.1]octa-2,5-diene. The was designed by Dr. Christoph Selg. More information can be found Full Paper E. Hey-Hawkins et al. (DOI: 10.1002/chem.202100898).
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ژورنال
عنوان ژورنال: Chemistry: A European Journal
سال: 2021
ISSN: ['0947-6539', '1521-3765']
DOI: https://doi.org/10.1002/chem.202101356